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The role of polymers in cycling, canoeing and badminton

Polymers are often trialed in sport for properties which can be beneficial in other areas of science and technology. So, let’s look more closely at some specific examples. The following polymer, known as Vectran, is a perfect example of how polymers tested in sports equipment can find applications in other industries.

Vectran is a polyester characterised by aromatic rings on both monomer constituents. It has a relatively high melting point of 276-330 °C, depending on the thickness of the strand, and resists creep, a property where ropes and cables deform over time due to the tensile pressure placed on them. In sporting equipment Vectran was first introduced as synthetic stringing for badminton racquets. The notable impact resistance and high tensile strength results in a strong yet lightweight head which allows for more powerful shots by the player. A 67 centimeter racquet can weigh as little as 87 grams!

The synthesis of Vectran

In both high performance and non-competitive canoeing carbon fibre reinforced polymer (CFRP) is the optimal construction material for canoe paddles and oars. Poly(acrylonitrile) is the main polymeric component of carbon fibre. The poly(acrylonitrile) fibres are spun before being heated in air, fusing the polymer into a series of pyridine rings at approximately 700 °C.

Radical polymerisation of acrylonitrile Cyclisation and dehydrogenation of poly(acrylonitrile)

Slowly heating the polymer at 600 °C expels hydrogen gas and fuses adjacent polymer chains together. At conditions up to 1300 °C multiple chains can fuse together, eliminating more hydrogen and nitrogen leaving a pure sheet of interlinked carbon atoms. The high temperatures and pressures involved in this process align the microscopic crystals which the carbon sheets form all along the same axis as the fibre. As such the overall structure is very resistant to bending or stretching pressures.

The formation of carbon fibre

Mixing with an epoxy resin will add further strength to the carbon fibre structure and allow for it to be coated in abrasion or further chemically resistant layers. Epoxy resins are very strong polymers that can withstand high temperatures. They are formed by the nucleophilic attack of phenols (or deprotonated phenols) on epoxides, leading to opening of the strained three-membered ring. This forms a prepolymer that can be reacted with nucleophiles, such as triamines (e.g. H2NCH2CH2NHCH2CH2NH2) – each of the three amine groups can react with an epoxide on a prepolymer. As the three amine groups can each react with different molecules of the pre-polymer, this forms a densely cross-linked structure that is very strong.

Formation of an epoxy resin

Alternatively, polycarbonates contain the carbonate functional group (O-(C=O)-O) and are commonly formed from acid chloride (RCOCl) precursors and bisphenol A. The monomers are linked together by multiple nucleophilic acyl substitutions where HCl is lost as a by-product. The resultant polymer layers are flexible and non-brittle; properties that allows them to be moulded into shape as a solid sheet without cracking or breaking, such as canoe and kayak hulls.

Formation of a polycarbonate by multiple nucleophilic acyl substitution reactions

This property is also desirable in safety equipment used in both cycling and motorcycling crash helmets. The outermost polycarbonate “shell” is able to absorb some of the impact energy by deforming and flexing slightly. Were the shell too rigid it would either be brittle and shatter or transfer much of the impact energy to your skull inside the helmet. As such the slightly malleable (pliable) polycarbonate shell absorbs much of the initial impact with a soft, foam, expanded polystyrene (EPS) interior to mitigate any remaining energy from a collision.

Further research into polymers continues to inspire cutting edge breakthroughs in both pure chemistry and applications in medical and industrial settings. For example, research has suggested that nanotubes, involving compact tubes of bonded carbon atoms, has a variety of potential applications such as; a super-strong industrial fibre, an alternative to copper conduction wire, and a novel delivery method for targeted chemotherapy.

The structure of carbon nanotubes

Take a look at one of our undergraduate videos, on badminton, made as part of a first year undergraduate macromolecules course.

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Exploring Everyday Chemistry

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